Soil Science

Kaolinite

StructureΒ 

Kaolinite is the commonest 1:1 silicate clay mineral found in soils.

What holds kaolinite crystals together?

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Interlayer bonding - The surface OH groups hold neighboring kaolinite layers together by forming relatively strong hydrogen bonds with oxygens on an adjacent tetrahedral sheet.

The diagram shows how the kaolinite layers are stacked to make clay crystals. OH groups are located on the outer surface of the octahedral sheet. Near the edges of crystals, these can dissociate to give each layer a small charge, which varies with soil pH.

Polyhedral view

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Space-filling view

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Properties

Occurrence - Kaolinite is the most widespread soil clay mineral, especially in warm, humid climates, and soils subject to moderate to strong leaching (e.g., podzolics, krasnozems). Potter's clay is mainly kaolinite.

Crystal size - Large (but still clay-sized)

Cation exchange properties - CEC ~ 0.02 - 0.06 moles charge per kg. This is low. Kaolinite crystals have little permanent charge. However, they do have a variable charge resulting from dissociation of surface hydroxyl groups.

Swelling when wet - Kaolinite swells relatively little. Hydrogen bonds between crystal layers inhibit expansion because the bonds are relatively strong.

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