Soil Science

Soil Colloids

Colloids are particles 0.002 mm in diameter. Soil colloids can therefore be equated to the clay particle size fraction, and are smaller than silt (0.002 to 0.02 mm) or sand (0.02 to 2 mm). They are composed of clay minerals (kaolinite, montmorillonite, etc) or soil organic matter. The chemical reactions that take place between the surfaces of soil colloids and the soil solution are of great significance in the chemistry of soil.

Soil colloids are highly chemically reactive (1) because of their specific surface area, and (2) because they carry electrical charges.

Specific suface area

The specific surface area of colloids can be illustrated by an example.

Imagine a sand sized cube with sides each 1 mm.

It has a surface area = 6 x 1 = 1 mm2 = 6 mm.

 
 

Now cut it up into colloidal sized cubes with sides of length 0.001 mm. There will be 1000^3 = 10^9 little cubes. Calculate the new surface area then click on one of the answer buttons.?

Correct! The surface area = 10^9 x 6 x 0.001 x 0.001 mm = 6000mm^2. The surface area has increased by a factor of 1000. Colloids are characterised by high surface area per unit mass (termed specific surface area).

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Colloid charge

The other important property of soil colloids is that they are usually electrically charged. There are two ways that this can happen. A permanent charge, or a variable charge.

Permanent Charge: Silicate clay minerals are built from tetrahedrons and octahedrons of oxygen anions (o2-). In soils the tetrahedron usually has a silicon cation (Si++) at its centre and the octahedron has an aluminium cation (A13+).

Look at the Soil Minerals module for more information on clay mineral structures.

Sheets

In a 2:1 silicate clay mineral crystal, Si tetrahedrons and Al octahedrons are arranged in sheets, as shown schematically below (look at the Soil Minerals module for an explanation). Within the sheets of these crystals, some of the Si and Al cations are permanently substituted by cations of lower valency, giving the crystal a net negative charge. This is called isomorphous substatution.

Unsubstituted

Substitution diagram

A13+ for Si4+

Substitution diagram

Mg2+ for A13+

Substitution diagram

Variable charges

Variable charges arise when H+ or OH- ions from the soil solution react with hydrosyl (-OH) groups at the colloid surface.

[Colloid]--OH + OH⁻ ⇌ [Colloid]--O⁻ + H₂O

[Colloid]--OH + H⁺ ⇌ [Colloid]--OH₂⁺

Kaolinite, sesquionides and humus have abundant surface hydrosyl groups, and variable charge is the main source of charge for these colloids. It is also the origin of positive charges on soil colloids. The term variable is used because the charge varies, particularly with pH.

 
 

If the pH of the soil falls, will negative variable charge on the colloids, decrease, remain constant or increase? Click on the correct answer.?

Correct! The negative charge will decrease. Lower pH implies a greater H^+ and lower OH^- concentration in the soil solution, which will result in more positive charges and less negative charges on the soil colloids.

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