Soil Science

Sesquioxide

What are sesquioxides?

The most common non-silicate clay minerals in soils are the oxide and hydroxide minerals of Fe and Al. These are often referred to as sesquioxides. Sesquioxides are particularly abundant in highly weathered soils (see Weathering in the Soil Genesis). Below are three common sesquioxides.

Think about the name and composition of each:

Goethite FeOOH

Gibbsite Al(OH)₃

Hematite Fe₂O₃

Fe³⁺ oxide minerals are rusty-colored (red, yellow, brown) or black. Hematite is named for its blood-red color. Al compounds are white or colorless.

Gibbsite

Gibbsite accumulates in old, highly weathered soils because of its low solubility and its resistance to leaching (Look at Weathering in Soil Genesis). It is common in the humid tropics.

As with the other sesquioxides, gibbsite crystals acquire small negative or positive charges by the reaction of the surface OH⁻ ions with H⁺ ions from the soil solution.

Sesquioxide CECs are low (about 0.005 moles of charge per kg).

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Crystals of gibbsite comprise stacks of octahedral sheets, with Al³⁺ at the octahedral centers and OH⁻ at the vertices.

Hematite and goethite

Red colors in soils are mostly caused by hematite, and yellow-brown colors are often caused by goethite. These Fe oxide minerals are formed when dissolved Fe²⁺ ions are oxidized to Fe³⁺ and precipitated (look at Waterlogging in Soil Genesis).

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